Review of the phase change material (PCM) usage for solar domestic water heating systems (SDWHS)

The shortage in energy resources combined with the climb in greenhouse emissions is the main incentive beyond the deployment of solar energy resource in various applications. One of the most successful applications is the utilization of solar energy in the domestic water heating systems (DWHS) because 70% of the consumed energy in the residential segment is utilized for space heating and appliances in cold climates 1 . However, the full deployment of solar energy in domestic water heating is only possible when an energy storage system with acceptable price is available. Recently a new tendency for deploying phase change materials (PCMs) as an energy storage system is introduced in several solar DWHS. These systems are known as integrated PCM in solar DWHS and offer several advantages including high storage capacity, low storage volume, and isothermal operation during the charging and discharging phases. The present study reviews various techniques utilized for integrating the PCM in solar water heating systems and the utilized methods for enhancing the heat transfer characteristics of the PCM through the usage of extended surfaces and high conductive additives. Copyright © 2017 John Wiley & Sons, Ltd.     

Numerical study on premixed hydrogen/air combustion characteristics and heat transfer enhancement of micro-combustor embedded with pin fins

Aimed at improving the energy output performance of the Microthermal Photovoltaic (MTPV) system, it is necessary to optimize the structure of the micro combustor. In this paper, micro combustor with in-line pin fins arrays (MCIPF) and micro combustor with both end-line pin fins arrays (MCEPF) were presented to realize the efficient combustion and heat transfer enhancement, and the influence of inlet velocity, equivalent ratio, and materials on thermal performance was investigated. The results showed that pin fins embedding is beneficial to improving combustion, and the combustion efficiency of MCIPF and MCEPF reaches 98.5% and 98.7%, which is significantly higher than that of the conventional cylindrical combustor (MCC). However, with the increase of inlet velocity from 8 m/s to 14 m/s, MCIPF exhibits the highest external wall temperature with a range of (1302–1386 K), while MCEPF maintains the best temperature uniformity. As the inlet velocity increases to 10 m/s, the external wall temperature and temperature uniformity reach the optimum. Besides, under the conditions of different equivalence ratios, both external wall temperature and heat flux increases first and then decreases, meanwhile the temperature uniformity of MCEPF is significantly improved compared with that of MCIPF, they all exhibit the highest external wall temperature with an equivalence ratio of 1.1, and the thermal performance is greatly enhanced. By comparing the heat transfer performance of combustors with different materials based on MCEPF, it is interesting to find that the application of high thermal conductivity materials can not only increase the external wall temperature, but also improve the temperature uniformity. Therefore, materials with high thermal conductivity such as Aluminum, Red Copper and Silicon Carbide should be selected for application in micro combustors and their components. The current work provides a new design method for the enhanced heat transfer of the micro combustor.     

Underwater image enhancement with global–local networks and compressed-histogram equalization

Due to the light absorption and scattering, captured underwater images usually contain severe color distortion and contrast reduction. To address the above problems, we combine the merits of deep learning and conventional image enhancement technology to improve the underwater image quality. We first propose a two-branch network to compensate the global distorted color and local reduced contrast, respectively. Adopting this global–local network can greatly ease the learning problem, so that it can be handled by using a lightweight network architecture. To cope with the complex and changeable underwater environment, we then design a compressed-histogram equalization to complement the data-driven deep learning, in which the parameters are fixed after training. The proposed compression strategy is able to generate vivid results without introducing over-enhancement and extra computing burden. Experiments demonstrate that our method significantly outperforms several state-of-the-arts in both qualitative and quantitative qualities.     

Equilibria,kinetics and mechanism for the degradation of the cytotoxic compound L-NG-nitroarginine

L-N^G-nitroarginine (LNNA), an analog of L-arginine, is a competitive inhibitor of nitric oxide synthase which causes the selective reduction of blood flow to tumor cells. Despite the potential of LNNA to function as an adjuvant in cancer therapies, its poor solubility and stability have hindered the development of an injectable formulation of LNNA that is suitable for human administration. This work, for the first time, details a systematic study on the determination of equilibrium K_a constants and the rate law of LNNA degradation. The four K_a values of LNNA were determined to be 1.03, 1.10?×?10^?2, 2.51?×?10^?10, and 1.33?×?10^?13 M. From the kinetic and equilibrium studies, we have shown that the deprotonated form of LNNA is the main form of LNNA that undergoes degradation in aqueous media at room temperature. The rate law of LNNA degradation was found to be first order with respect to OH^? concentration and first order with respect to LNNA^? concentration. The rate constant at 25?°C and 1?atm was determined to be 0.04453 M^?1min^?1. A base catalyzed mechanism of LNNA degradation was proposed based on the kinetic study. The mechanism was found to be very useful in explaining the discrepancies and changes of the rate law at different pH values. It is thus recommended that LNNA should be formulated as a concentrated solution in acidic conditions for maximum chemical stability during storage and be diluted with a basic solution to near physiological pH just before administration.     

Numerical simulation and experimental research on heat transfer and flow resistance characteristics of asymmetric plate heat exchangers

The asymmetric plate heat exchanger (APHE) has the possibility of achieving balanced pressure drops on both hot and cold sides for situations with unbalanced flow, which may in turn enhance the heat transfer. In this paper, the single-phase water flow and heat transfer of an APHE consisted of two types of plates are numerically (400≤Re≤12000) and experimentally (400≤Re≤ 3400) investigated. The numerical model is verified by the experimental results. Simulations are conducted to study the effects of N, an asymmetric index proposed to describe the geometry of APHEs. The correlations of the Nusselt number and friction factor in the APHEs are determined by taking N and working fluids into account. It is found that an optimal N exists where the pressure drops are balanced and the heat transfer area reaches the minimum. The comparison between heat transfer and flow characteristics of the APHEs and the conventional plate heat exchanger (CPHE) is made under various flow rate ratios of the hot side and the cold side and different allowable pressure drops. The situations under which APHE may perform better are identified based on a comprehensive index Nu/f^1/3.     

Underwater image quality enhancement through integrated color model with Rayleigh distribution

The physical properties of water cause light-induced degradation of underwater images. Light rapidly loses intensity as it travels in water, depending on the color spectrum wavelength. Visible light is absorbed at the longest wavelength first. Red and blue are the most and least absorbed, respectively. Underwater images with low contrast are captured due to the degradation effects of light spectrum. Therefore, the valuable information from these images cannot be fully extracted for further processing. The current study proposes a new method to improve the contrast and reduce the noise of underwater images. The proposed method integrates the modification of image histogram into two main color models, Red–Green–Blue (RGB) and Hue-Saturation-Value (HSV). In the RGB color model, the histogram of the dominant color channel (i.e., blue channel) is stretched toward the lower level, with a maximum limit of 95%, whereas the inferior color channel (i.e., red channel) is stretched toward the upper level, with a minimum limit of 5%. The color channel between the dominant and inferior color channels (i.e., green channel) is stretched to both directions within the whole dynamic range. All stretching processes in the RGB color model are shaped to follow the Rayleigh distribution. The image is converted into the HSV color model, wherein the S and V components are modified within the limit of 1% from the minimum and maximum values. Qualitative analysis reveals that the proposed method significantly enhances the image contrast, reduces the blue-green effect, and minimizes under- and over-enhanced areas in the output image. For quantitative analysis, the test with 300 underwater images shows that the proposed method produces average mean square error (MSE) and peak signal to noise ratio (PSNR) of 76.76 and 31.13, respectively, which outperform six state-of-the-art methods.     

Structures and electrical conductivities of Gd3+ and Fe3+ co-doped cerium oxide electrolytes sintered at low temperature for ILT-SOFCs

Gd³⁺ and Fe³⁺ co-doped cerium oxide electrolytes, Ce_0.9Gd_0.1‐xFe_xO_2-δ (x?=?0.00, 0.01, 0.03, 0.05, 0.07, 0.10), were prepared by co-precipitation for ultrafine precursor powders and sintering for densified ceramic pellets. The crystal and microscopic structures were characterized by XRD, FESEM and Raman spectroscopy and their electrical properties were studied by AC impedance spectroscopy and the measurement of single cell's outputs. In comparison with Ce_0.9Gd_0.1O_1.95, the ceramic pellets of Ce_0.9Gd_0.1‐xFe_xO_2-δ with a relative density of 95% can be obtained after sintered at 1000?°C for 5?h, showing a remarkably enhanced sintering performance with a sintering temperature reduction of 500?°C, which might be ascribed to the highly activated migration of constituent species in the cerium oxide lattice doped with Gd³⁺ and Fe³⁺ions. Moreover, the electrical conductivity of Ce_0.9Gd_0.1‐xFe_xO_2-δ can be significantly enhanced depending on the mole fraction x, with Ce_0.9Gd_0.07Fe_0.03O_1.95 exhibiting the highest electrical conductivity of 38 mS/cm at 800?°C, about 36% higher than that of Ce_0.9Gd_0.1O_1.95 electrolyte sintered at 1500?°C for 5?h. So, The Gd³⁺ and Fe³⁺ co-doped cerium oxide would be an excellent candidate electrolyte for ILT SOFCs due to its prominent sintering performance and enhanced electrical conductivity.     

Boosting cell performance and fuel utilization efficiency in a solar assisted methanol microfluidic fuel cell

Solar generated hydrogen from an optimized P25 thin film of 3.2 mg/cm² with 0.25% of platinum as co-catalyst improves the peak power output of a methanol microfluidic fuel cell operated with a methanol to water ratio of 1:1 almost ninefold, from 22 mW/cm² to 213 mW/cm². Different methanol to water ratios in the fuel tank generate similar amounts of hydrogen, but the cell performance has large variations due to the different oxidation kinetics of hydrogen and methanol in the fuel breathing anode, resulting in a mixed-potential anodic performance. The trade-off between power output and fuel utilization diminishes in this system. The methanol utilization efficiency at peak power operation increases from 50% (for 0.2 V) to 78% (for 0.5 V) for methanol to water ratio of 1:1. The result indicates that in-situ generation of hydrogen by solar light can be applied to both portable and large-scale stationary fuel cells.     

Enhanced heat transfer in rectangular duct with punched winglets

Thermal performance of a heat exchanger duct with punched winglets(PWs) mounted on the upper duct wall has been examined for Reynolds number(Re) ranging from 4100 to 25,500. In the present experiment, two types of PWs: punched delta-and elliptical-winglets(P-DW and P-EW) with four punched-hole sizes were tested at a fixed attack angle, optimal relative pitch and height. Also, data of solid delta-and elliptical-winglets(DW and EW) were included for comparison. The investigation has shown that the P-DW yields higher thermal-performance enhancement factor(η) than the P-EW. Although the solid DW and EW with no punch have the highest heat transfer and friction loss, the PWs yield better η than the solid ones. For PWs, the P-DW with smaller hole size has the peak heat transfer and friction loss around 5.7 and 40 times over the smooth duct, respectively but the optimum η of 2.17 is seen for the one with a certain hole size. The PWs provide η at about 5%–8% above the solid winglets.